How to select inks for food packaging?
In this article, Siegwerk’s Jatin Takkar evaluates different food packaging applications with regards to the potential migration risk of the packaging structure, and guides on the selection of ink for the application and packaging material combination
30 Jun 2017 | By WhatPackaging? Team
Let us first look at categories with migration risk
The following table gives a non-exhaustive overview on the major packaging categories with risk of migration, set-off and/or organoleptic deterioration, as well as recommendations with regard to the selection of ink types and validation measures by the printer.
In case of packaging with an identified migration risk, only inks and varnishes explicitly intended for food packaging should be used.
Special attention must be paid to applications subject to high temperature exposure, such as pasteurisation, sterilisation (dry or in an autoclave), microwave or baking oven. To prevent migration of cleavage products from certain yellow, orange or red pigments, selection of special ink shades, based on appropriate high-performance pigments, may be required. This applies especially if the packed food will be subject to more than 200 °C in a microwave or baking oven; equally a particular choice of alternatives is necessary if food is to be boiled, pasteurized, sterilized, or cooked in a microwave or baking oven, and is packed in structures which do not provide a functional barrier to migration.
A printer should additionally use the checklist: “Processes and Parameters which potentially trigger non-compliance [sic] (migration, organoleptic effect)” for verifications (see article Compliance: Ink migration in food packaging). Packaging intended for particularly sensitive consumer groups (such as infants and small children) requires formal qualification in any case.
| Flexible Packaging | ||||||
| Application | Sandwich print in laminates or surface print on monofilm WITHOUT the inner layer(s) being a barrier to migration | Thermally treated packed food. Sandwich print in laminates or surface print on monofilm WITHOUT the inner layer(s) being a barrier to migration | Surface print monofilm and liddings WITH the inner layer(s) being a barrier to migration | Sandwich print in laminates WITH the inner layer(s) being a barrier to migration | ||
| Examples | Cheese, meat products, tea bags, confectionery, bakery products, butter wrappers | Ready meals, bakery, pasteurized, sterilized dry or in an autoclave, boil-in-the-bag, microwaveable | Dairy products (aluminum lids) | Meat products, ready meals, soups, spices, coffee, tea, preserved food, packed in laminates with aluminum foil | ||
| Potential migration risk of the packaging structure | Yes, migration both via diffusion across the layers and via set-off. | Yes, migration both via diffusion across the layers and via set-off. Migration can be enhanced by temperature, pressure and water/steam distillation. | Yes, migration via set-off to high absorbance layer (heatseal varnish, PE …). | Yes, migration via outer layer(s) and set-off. | ||
| About inks for this application | Solvent-based and water-based Only products intended for food packaging. | UV curing Only products intended for food packaging (‘low migration’) No UV curing products for small packaging for food for infants and small children. | Solvent-based and water-based Only products intended for food packaging. | Solvent-based and water-based Only products intended for food packaging. | UV curing Only products intended for food packaging (‘low migration’) No UV curing products for small packaging for food for infants and small children. | Solvent-based and water-based Only products intended for food packaging. | 
| Measures recommended to the printer | Calculate migration of actual combination of products on specific packaging using Siegwerk Statements of Composition. Consider qualification via migration testing order upon previous Siegwerk disclosure to intended lab. | Formal qualification via migration testing order upon previous Siegwerk disclosure to intended lab. | Calculate migration of actual combination of products on specific packaging using Siegwerk Statements of Composition. Consider qualification via migration testing order upon previous Siegwerk disclosure to intended lab. Observe chapter 6.2.1 | Calculate migration of actual combination of products on specific packaging using Siegwerk Statements of Composition. Consider qualification via migration testing order upon previous Siegwerk disclosure to intended lab. | Formal qualification via migration testing order upon previous Siegwerk disclosure to intended lab. | Calculate migration of actual combination of products on specific packaging using Siegwerk Statements of Composition. | 
| Rigid Liquid Food Packaging | Self-Adhesive Labels, Cups, Tags , Sleeves, Tubes | ||||
| Application | PE-coated board packaging WITH or WITHOUT the inner layer(s) being a barrier to migration | Application | In-mold labels (IML) for cups, tubs, trays WITH or WITHOUT the inner layer(s) being a barrier to migration | Sleeves or glued or pressure-sensitive adhesive (PSA) labels, laminated or not laminated, for cups, tubs, trays | |
| Examples | Milk and fruit juice cartons, sauces, soups | Examples | Dairy products, sauces | Dairy products, sauces | |
| Potential migration risk of the packaging structure | Yes, migration via diffusion and/or set-off to high absorbance PE layer | Potential migration risk of the packaging structure | Yes, migration via diffusion and set-off. Label will be melted on the container and become a primary food packaging which is stacked before filling | Yes, migration via diffusion and set-off. Sleeve or label will be applied onto the container and become a primary food packaging which is stacked before filling | |
| About inks for this application | Water-based, solvent-based, UV curing, electron beam curing Only products intended for food packaging (UV: ‘low migration’). By default, no UV curing products for small packaging for food for infants and small children. | About inks for this application | UV curing, oleoresinous offset, water-based overcoatings Only products intended for food packaging (‘low migration’). | UV curing Only products intended for food packaging (‘low migration’). | |
| Measures recommended to the printer | Calculate migration of actual combination of products on specific packaging using Siegwerk Statements of Composition. Formal qualification via migration testing order upon previous Siegwerk disclosure to intended lab. | Measures recommended to the printer | Formal qualification via migration testing order upon previous Siegwerk disclosure to intended lab. | Formal qualification via migration testing order upon previous Siegwerk disclosure to intended lab. | |
| Self-Adhesive Labels, Cups, Tags , Sleeves, Tubes | |||||
| Application | Glued or PSA labels for primary packaging and lidding | Shrink sleeves on PET bottles | Shrink sleeves on PE/PP/OP bottles | Tubes, cups | |
| Examples | Labels applied on filling line to preformed and filled packaging of all types of food. | Soda, mineral water. | Dairy food, fruit drinks. | Mayonnaise, mustard, dairy products. | |
| Potential migration risk of the packaging structure | Yes, depending on barrier properties to migration of the primary packaging: migration via diffusion (set-off not possible). | Minor, studies show that PET is quite a barrier to migration from printed layers. | Yes, migration via diffusion across PE/PP/OPS is possible. | Yes, depending on point in time of tube formation and on presence of barrier: migration via diffusion and/or set-off. | |
| About inks for this application | UV curing Products intended for food packaging (‘low migration’) highly recommended. In any case, odor optimized products (‘low odor’) recommended. | Water-based, solvent-based Products intended for food packaging recommended. | UV curing (cationic UV flexo, radical UV offset and flexo) Products intended for food packaging (‘low migration’) highly recommended. In any case, odor optimized products (‘low odor’) necessary. | UV curing Only products intended for food packaging (‘low migration’). | UV curing Only products intended for food packaging (‘low migration’). | 
| Measures recommended to the printer | Individual case to be assessed. In any case, consider formal qualification via migration testing order upon previous Siegwerk disclosure to intended lab.Sensorial issues to be considered. | Individual case to be assessed. Consider calculating migration of actual combination of products on specific packaging using Siegwerk Statements of Composition. | Individual case to be assessed. In any case, consider formal qualification via migration testing order upon previous Siegwerk disclosure to intended lab Sensorial issues to be considered. | Formal qualification via migration testing order upon previous Siegwerk disclosure to intended lab. | Formal qualification via migration testing order upon previous Siegwerk disclosure to intended lab. | 
| Paper and Board Packaging | |||||||
| Application | Rigid packaging, tags, trays WITHOUT the inner layer(s) being a barrier to migration | Rigid packaging WITHOUT the inner layer(s) being a barrier to migration | Paper packaging WITHOUT the inner layer(s) being a barrier to migration | ||||
| Examples | Folding carton (with or without PE or varnish coating) for fast food, frozen food, confectionery, bakery, dry pasta, rice, sugar, cereals, vegetables, fruits, tea tags. | Some use for ready meals for microwave and baking oven. | Corrugated board boxes for pizza, fast food, bakery. | Folding carton with dry food (cereals) in PE, PP or paper bag inside the box, with air room between the two packages. | Paper bags for bakery, confectionery, sugar, flour, fruits, vegetables, wrappers (with or without PE or varnish coating) for fast food cheese, meat. Some use for microwave. | ||
| Potential migration risk of the packaging structure | Yes, migration both via diffusion across the layers, via set-off and gas phase. Migration can be enhanced by temperature and water/steam distillation. | Yes, migration via diffusion & gas phase, or via set-off, diffusion & gas phase | Yes, migration via diffusion & gas phase, or via set-off, diffusion & gas phase. Migration can be enhanced by temperature and exposure to water/steam. | ||||
| About inks for this application | UV curing Only products intended for food packaging (‘low migration’) UV curing products for thermally treated food (microwave, baking oven) and for small packaging for food for infants and small children | Oleoresinous offset Only products intended for food packaging (‘low migration’) | Water-based Only products intended for food packaging | UV curing Only products intended for food packaging (‘low migration’) UV curing products for small packaging for food for infants and small children | Oleoresinous offset Only products intended for food packaging (‘low migration’) | Water-based Only products intended for food packaging | Water-based Only products intended for food packaging | 
| Measures recommended to the printer | Formal qualification via migration testing order upon previous Siegwerk disclosure to intended lab. | Calculate migration of actual combination of products on specific packaging using Siegwerk Statements of Composition. Consider qualification via migration testing order upon previous Siegwerk disclosure to intended lab. For microwave and baking oven, read article: Compliance: Ink migration in food packaging | Calculate migration of actual combination of products on specific packaging using Siegwerk Statements of Composition. Consider qualification via migration testing order upon previous Siegwerk disclosure to intended lab.
 For microwave and baking oven, read article: Compliance: Ink migration in food packaging | Calculate migration of actual combination of products on specific packaging using Siegwerk Statements of Composition. Consider qualification via migration testing order upon previous Siegwerk disclosure to intended lab.
 For microwave and baking oven, read article: Compliance: Ink migration in food packaging | Calculate migration of actual combination of products on specific packaging using Siegwerk Statements of Composition. Consider qualification via migration testing order upon previous Siegwerk disclosure to intended lab. | Calculate migration of actual combination of products on specific packaging using Siegwerk Statements of Composition. Consider qualification via migration testing order upon previous Siegwerk disclosure to intended lab. | Calculate migration of actual combination of products on specific packaging using Siegwerk Statements of Composition. Consider qualification via migration testing order upon previous Siegwerk disclosure to intended lab. For microwave and baking oven, read article: Compliance: Ink migration in food packaging | 
Categories without migration risk
| Paper & Board Packaging | Self-Adhesive Labels, Sleeves | |||
| Application | Rigid packaging WITH the inner wrap being a barrier to migration | PSA labels for primary packaging and lidding WITH the inner wrap or the lidding being a barrier to migration |  Shrink sleeves on glass bottles | |
| Examples | Cereal in a laminate OPP/aluminum foil/PE bag inside the box. | Labels applied on filling line to preformed and filled packaging/lidding with aluminum foil layer, i.e. labeled ready meal packs or aluminum tubs. | Soda, mineral water, alcoholic beverages. | |
| Potential migration risk of the packaging structure | No. Food is completely tight-sealed against migrants coming through the air room between the two packages. | No. Aluminum foil prevents diffusion migration, and set-off is not possible15. | No. Glass is by default a recognized functional barrier. | |
| About inks for this application | UV Curing, oleoresinous offset, water-based In any case, odor optimized products (‘low odor’) necessary. | UV Curing, oleoresinous offset, water-based In any case, odor optimized products (‘low odor’) necessary. | UV curing (cationic UV flexo, radical UV offset and flexo) In any case, odor optimized products (‘low odor’) necessary. | |
| Measures recommended to the printer | If the layer eligible for being a functional barrier is not aluminum foil (i. e. vacuum deposited aluminum on PET is not necessarily a barrier): formal qualification via migration testing order upon previous Siegwerk disclosure to intended lab. Sensorial issues to be considered. | Sensorial issues to be considered. | Sensorial issues to be considered. | |
Cases of unintentional and intentional direct food contact
Particular cases of unintentional but foreseeable direct food contact of the printed ink layer
There are cases where unintentional but foreseeable direct contact of the printed and dried or cured ink and/or varnish layer to the food is possible. This is associated with a higher risk for the consumer as there is no barrier function of the packaging material between ink and food.
Some examples:
Lamination print job where the printed layer may be exposed to food at the cutting edges, or
a packaging line where wrappers of food packages are partly folded so that a small area of the printed surface is turned inside (e.g. butter wrappers), or
food that could be spilled onto a surface print upon opening of the package by the consumer (who may lick it off), or
articles with transient food contact like napkins, placemats, tea tags and others.
In accordance with Good Manufacturing Practice principles, Siegwerk recommends precautionary measures to the converter to minimize the risk of migration. Otherwise, colored matter could end up in food (so-called ‘bleeding’), and/or non-visible migration could occur via solubilization of the printed layers. To prevent any risk of bleeding and solubilization, the resistances of the printed layers to the relevant foods are to be guaranteed as measured by the relevant fastness standards:
ISO 2836 (Assessment of print resistance to various agents; in particular with regard to water, oils and fats, cheese and spices),
ISO 11628 (Determination of print resistance to acids)
EN 646 (Paper and board intended to come into contact with foodstuffs – determination of color fastness of dyed paper and board) for towels and napkins.
The printer is responsible for the selection of printing inks and varnishes which are resistant to the respective foodstuff. To the extent that the information is not already declared in Siegwerk’s Technical Data Sheets and related documentation, the required typical fastness data is available on request. As a further measure, Siegwerk recommends the assessment of potential migration of the relevant migrants via a worstcase calculation or – preferably – via a practical migration test.
Direct food contact applications
In the vast majority of food packaging structures, the printing ink is applied to that side of the packaging which is not in direct contact with the packed food. But there are some instances with intended direct food contact of printing inks (or protective coatings, heat-seal coatings, anti-fog coatings or slip coatings). It is obvious that in comparison with non-food prints there is a massively increased risk of migration into the food.
In Europe, today, in the absence of specific legislation concerning printing ink products intended for direct food contact, only raw materials are used that are included in positive lists and/or have been evaluated by a recognized expert body. However, the situation is about to change: the German Ordinance on Printing Inks will provide a positive list of substances that are allowed to be used for direct food applications as long as the given migration limits are met.
Under FDA provisions, direct food contact refers to a printing ink or coating (e.g. protective, sealing, antifog, slip lacquers) that is intended by design to be in direct contact with a food product. By virtue of this intimate contact, components of the printing ink or coating have the potential to migrate to food and, therefore, must be in compliance with the indirect food additive guidelines at 21 CFR Parts 173-178. Indian Standard IS 15495 addresses also printing inks and varnishes for direct food contact. It is stipulated that, “if for some specific requirements it is necessary for the printed surface to be in contact with food, the printing inks shall be formulated with materials which are acceptable as food additives” and “produce a non-toxic printed surface that complies with the appropriate regulations”.
In any case, for such critical DFC applications, the printer is advised to use only designated inks for intended direct food contact and to safeguard with great care that no inacceptable migration takes place under the foreseeable conditions of use.
 
                                 
                             
                             
                                                
 
                                             
                                             
                                             
                                             
                                            



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