Colour Management - Part Thirteen
Kiran Prayagi, print technologist and chairman, Graphic Art Technology & Education demystifies colour management in a series of articles. In this tenth article, he discusses pigments and dyes - deficiency.
30 Jul 2013 | 4200 Views | By Kiran Prayagi
      Article five in this series outlined some basic problems in colour reproduction. Also explained
      
      was the differences in the colour reproduction systems and the colour perception by the
      
      human eye. That is the first stage where faulty colours began to appear in the reproduction
      
      systems. The second most important problem comes from the pigments and dyes used. All
      
      suffer from some deficiencies that result in faulty colours unless some corrections are applied
      
      in the process. In analogue photography and the printing processes CMY and CMYK
      
      colorants are used, respectively. The ideal colorants are as shown in figure 1.
      
      
      
      
      
      
      
      
      
      Looking at the visual colour spectrum and divided onto 3 sections of roughly 100 nanometers
      
      each, the first one third appears blue, the middle one third green, and the last one third red.
      
      These correspond to the basic colours of additive principles. When two thirds of the visible
      
      spectrum is perceived the two basic colours combine to give one secondary colour that
      
      correspond to cyan, magenta or yellow. The concept of ‘grey error’ and ‘hue error’ was
      
      explained in article 10. With ideal colorants shown in figure 1 the reflecting colours are have
      
      full energy and are reflected 100 percent and remaining one third is fully absorbed. The same
      
      is indicated in figure 2 in a different way. Figure 2 shows full reflection of red, green, blue
      
      colours from white surface. The same amount of reflection of two primary colours is obtained
      
      
      Figure 3 indicates the deficiencies of cyan, magenta, yellow colorants as ‘hue error’ and ‘grey error’. To understand this better the following explanation may help. Compare figures 1 and 2 with 3 and 4.
      
      
      
      
      
      
      Yellow colorant absorbs blue light, magenta and yellow absorb green and blue, respectively.
      
      Absorption of this one third of the spectrum makes the colorant appeared coloured it shows. If
      
      the ideal colorant cyan is added with some quantity of ideal magenta and a little quantity of
      
      ideal yellow then in this combination cyan colorant will absorb red, some quantity of magenta
      
      will absorb green and a little quantity of yellow will absorb blue. The available cyan colorant
      
      behaves exactly in this fashion as if it has contamination of magenta and yellow colorants.
      
      If the ideal colorant magenta is added with some quantity of ideal yellow then in this
      
      combination magenta colorant will absorb green and some quantity of yellow will absorb
      
      blue. The available magenta colorant behaves exactly in this fashion as if it has contamination
      
      of yellow colorants.
      
      
       
      
      
      Yellow colorant is much better and very close to ideal yellow, hence deficiency can be disregarded.
      
      In actual fact, each of the three inks is contaminated with the other two, but at this stage to
      
      keep explanation understandable only major faults are highlighted. So when only available
      
      cyan colorant is deposited on the white surface it is as if cyan, magenta, and yellow are
      
      deposited as follows.
       
      
      Available cyan = C m y
      
      
      
      Similarly, for available magenta and yellow colorants
      
      Available magenta = My
      
      Available yellow = Y
       
      
      But the matter is more complicated and is actually as follows.
      
      Available magenta = Mcy
      
      Available yellow = Ycm
       
      
      Due to these ink deficiencies when equal quantity of available cyan, magenta, yellow
      
      colorants is mixed it works as follows.
      
      cyan (Cmy) + magenta (My) + Y = CMmYyy
       
      
      With equal quantities the combination has maximum percentage of yellow and a minimum
      
      percentage of cyan. This excess of yellow and then magenta makes combination appear
      
      reddish brown rather than grey. To convert this in to grey a higher quantity of cyan dye is
      
      used in the paper print and transparency photographs and a bigger dot of cyan in the printing
      
      processes compared to magenta and yellow.
       
      
      The explanation above relates mostly to ‘hue error’ of colorants. The ‘grey error’ make
      
      colours dirty to some extent and makes it difficult to obtain clean colours.
       
      
      To calculate the deficiencies precisely and apply correction mathematical analysis using
      
      measurement instruments is possible and has been used. See article 10. To successfully apply
      
      the rule of four as mentioned in article 11 colour correction is applied in the process.